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                  [1]鄭杰昌,魏勇,唐云濤,等.模板法制備空心球形Li4Ti5O12負極材料及其電化學性能研究[J].哈爾濱工程大學學報,2020,41(7):1094-1098.[doi:10.11990/jheu.201905012]
                   ZHENG Jiechang,WEI Yong,TANG Yuntao,et al.Preparation of Li4Ti5O12 hollow-sphere anode materials using the template method and their electrochemical properties[J].hebgcdxxb,2020,41(7):1094-1098.[doi:10.11990/jheu.201905012]
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                  模板法制備空心球形Li4Ti5O12負極材料及其電化學性能研究(/HTML)
                  分享到:

                  《哈爾濱工程大學學報》[ISSN:1006-6977/CN:61-1281/TN]

                  卷:
                  41
                  期數:
                  2020年7期
                  頁碼:
                  1094-1098
                  欄目:
                  出版日期:
                  2020-07-05

                  文章信息/Info

                  Title:
                  Preparation of Li4Ti5O12 hollow-sphere anode materials using the template method and their electrochemical properties
                  作者:
                  鄭杰昌1 魏勇2 唐云濤2 趙振博2 陳程成2
                  1. 國家市場監督管理總局缺陷產品管理中心, 北京 100820;
                  2. 工業和信息化部電子第五研究所, 廣東 廣州 510610
                  Author(s):
                  ZHENG Jiechang1 WEI Yong2 TANG Yuntao2 ZHAO Zhenbo2 CHEN Chengcheng2
                  1. Defective Product Administrative Center, State Administration for Market Regulation(SAMR), Beijing 100820, China;
                  2. China Electronic Product Reliability and Environmental Testing Research Institute(CEPREI), Guangzhou 510610, China
                  關鍵詞:
                  鈦酸鋰空心球形模板法負極材料鋰離子電池高倍率電化學鈦基氧化物
                  分類號:
                  O6
                  DOI:
                  10.11990/jheu.201905012
                  文獻標志碼:
                  A
                  摘要:
                  為提高鋰離子電池負極材料鈦酸鋰的倍率性能AG复古花园,本文采用軟模板法制備具有空心結構的鈦酸鋰(Li4Ti5O12),并研究了其電化學儲鋰性能AG复古花园。通過調節模板劑十二胺的添加量,控制形成空心球形結構的TiO2前驅體AG复古花园,再利用化學鋰化,制得繼承空心球形結構的Li4Ti5O12。XRDAG复古花园、SEM分析表明所制備的Li4Ti5O12為純相,且其形貌均勻,空心結構明顯。對其進行電化學性能測試表明:該空心球狀Li4Ti5O12電極材料具有優良的電化學性能,其首周容量為170 mAh/g,循環100周后容量仍能保持155 mAh/g以上,并且表現出優異的倍率性能AG复古花园,在5、20、80 C下的放電容量分別為135AG复古花园、115、100 mAh/g。

                  參考文獻/References:

                  [1] ARMAND M, TARASCON J M. Building better batteries[J]. Nature, 2008, 451(7179):652-657.
                  [2] LIU Jun, SONG Kepeng, VAN AKEN P A, et al. Self-supported Li4Ti5O12-C nanotube arrays as high-rate and long-life anode materials for flexible Li-ion batteries[J]. Nano letters, 2014, 14(5):2597-2603.
                  [3] CHOI N S, CHEN Zonghai, FREUNBERGER S A, et al. Challenges facing lithium batteries and electrical double-layer capacitors[J]. Angewandte chemie international edition, 2012, 51(40):9994-10024.
                  [4] GOODENOUGH J B, PARK K S. The Li-ion rechargeable battery:a perspective[J]. Journal of the American chemical society, 2013, 135(4):1167-1176.
                  [5] TANG Yufeng, HUANG Fuqiang, ZHAO Wei, et al. Synthesis of graphene-supported Li4Ti5O12 nanosheets for high rate battery application[J]. Journal of materials chemistry, 2012, 22(22):11257-11260.
                  [6] LI Xue, LIN Huangchang, CUI Wangjun, et al. Fast solution-combustion synthesis of nitrogen-modified Li4Ti5O12 nanomaterials with improved electrochemical performance[J]. ACS applied materials & interfaces, 2014, 6(10):7895-7901.
                  [7] CHEN Chengcheng, HUANG Yanan, AN Cuihua, et al. Copper-doped dual phase Li4Ti5O12-TiO2 nanosheets as high-rate and long cycle life anodes for high-power lithium-ion batteries[J]. ChemSusChem, 2015, 8(1):114-122.
                  [8] CHEN Chengcheng, HUANG Yanan, ZHANG Hao, et al. Small amount of reduce graphene oxide modified Li4Ti5O12 nanoparticles for ultrafast high-power lithium ion battery[J]. Journal of power sources, 2015, 278:693-702.
                  [9] LIN Zhiya, YANG Yanmin, JIN Jiamen, et al. Graphene-wrapped Li4Ti5O12 hollow spheres consisting of nanosheets as novel anode material for lithium-ion batteries[J]. Electrochimica acta, 2017, 254:287-298.
                  [10] SHI Yi, GAO Jie, ABRU?A H D, et al. Rapid synthesis of Li4Ti5O12/graphene composite with superior rate capability by a microwave-assisted hydrothermal method[J]. Nano energy, 2014, 8:297-304.
                  [11] SHEN Laifa, ZHANG Xiaogang, UCHAKER E, et al. Li4Ti5O12 nanoparticles embedded in a Mesoporous carbon matrix as a superior anode material for high rate lithium ion batteries[J]. Advanced energy materials, 2012, 2(6):691-698.
                  [12] JIA Rong, YUE Jili, XIA Qiuying, et al. Carbon shelled porous SnO2-δ nanosheet arrays as advanced anodes for lithium-ion batteries[J]. Energy storage materials, 2018, 13:303-311.
                  [13] SHA Yujing, YUAN Tao, ZHAO Bote, et al. Solid lithium electrolyte-Li4Ti5O12 composites as anodes of lithium-ion batteries showing high-rate performance[J]. Journal of power sources, 2013, 231:177-185.
                  [14] WU Zhongshuai, YANG Sheng, ZHANG Lili, et al. Binder-free activated graphene compact films for all-solid-state micro-supercapacitors with high areal and volumetric capacitances[J]. Energy storage materials, 2015, 1:119-126.
                  [15] ZHOU Le, ZHANG Xiaosong, HUANG Mengyi, et al. A facile way to prepare carbon-coated Li4Ti5O12 porous fiber with excellent rate performance as anode in lithium ion battery[J]. Electrochimica acta, 2018, 283:1418-1424.
                  [16] SUN Yunong, DONG Hui, XU Yunlong, et al. Incorporating cyclized-polyacrylonitrile with Li4Ti5O12 nanosheet for high performance lithium ion battery anode material[J]. Electrochimica acta, 2017, 246:106-114.

                  備注/Memo

                  備注/Memo:
                  收稿日期:2019-05-06AG复古花园。
                  基金項目:國家自然科學基金青年基金項目(21801048).
                  作者簡介:鄭杰昌,男,工程師;陳程成,男,工程師,博士.
                  通訊作者:陳程成,E-mail:chenchengcheng@ceprei.com.
                  更新日期/Last Update: 2020-08-15
                  AG复古花园

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